Material Research
GUI Yong, LIANG Zhiyuan, GUO Tingshan, WANG Mengyao, ZHAO Qinxin, WANG Shuo
Five typical heat-resistant materials T91, VM12, Super 304H, Inconel 617 and Sanicro 25 were selected as the experimental materials, and the supercritical carbon dioxide corrosion tests were conducted at 600 ℃ and 15 MPa. Analytical balance was used to obtain the weight gain changes of heat-resistant materials. Raman spectrometer, X-ray diffractometer and glow discharge spectrometer were employed to characterize the phase and composition of corrosion products on the surface of heat-resistant materials. Electron microscope was used to observe the surface and cross-section morphology.Finally, the corrosion behavior of heat-resistant materials was analyzed. Results show that T91 and VM12 obey the parabolic corrosion kinetic law, while Super 304H, Inconel 617 and Sanicro 25 have no obvious weight gain and no obvious law.The weight gain is inversely proportional to the Cr content of heat-resistant materials.The heat-resistant materials undergo oxidation and carburization reactions in a high-temperature supercritical carbon dioxide environment.T91 and VM12 have no Cr-poor phenomenon, while Super 304H, Sanicro 25 and Inconel 617 have obvious Cr-poor areas, and the thickness of Cr-poor areas from small to large is Inconel 617