Green Energy and Low-carbon Technology
LIANG Wuzhou, MA Suxia, FENG Yuchuan, LIU Zhongyuan, ZHAO Guanjia
In response to the national "dual carbon" policy, so as to reduce carbon dioxide emissions from coal-fired power plants, the co-combustion of coal and ammonia has received widespread attention. Based on molecular dynamic simulation, researches were conducted on the changes in the types and quantities of coal-ammonia pre-pyrolysis products at different temperatures, and the migration pathways of nitrogen element during pre-pyrolysis and combustion processes, so as to obtain the influence mechanism of pre-pyrolysis temperature on NOx emissions. Results show that, the increase of pre-pyrolysis temperature leads to the decrease of NOx emissions during combustion. Due to the increased temperature can enhance the interactions between coal and ammonia during pre-pyrolysis, the production of CN and HCN increases with the increase of pre-pyrolysis temperature, and the conversion of hydrogen atoms in coal into H2 is promoted by the interactions between coal and ammonia. Meanwhile, the increase of pre-pyrolysis temperature can promote the pyrolysis of NH3 to produce N2, reducing the nitrogen sources available for NOx formation. The reduction in NH3 content decreases the generation of HNO, thereby lowering NOx emissions. Additionally, the increase of pre-pyrolysis temperature can promote the production of H2. The presence of H2, on the one hand, can consume a large amount of O2, reducing the formation of NOx during combustion, on the other hand, can accelerate the conversion of HNO to N2, thus reducing the generation of NO from HNO decomposition.