Boiler Technology
NI Mingguo, LIN Liming, LIU Dunyu, JIN Jing, CHENG Qian, LI Wei
Based on higher oxygen release rate and better reaction performance of the coal ash rich in iron and calcium, the electronic paramagnetic resonance (EPR) spectroscopy was adopted to perform relevant tests and analyses. The high-iron high-calcium coal ash was mechanically mixed with starch, cement and ATP, respectively, and subsequently the mixtures were calcined and granulated, following which, the property of a new oxygen carrier (Ash7-ATP3) was analyzed for industrial application using a fluidized bed reactor. Results show that there are crystal defects (oxygen vacancies) in the high-iron high-calcium coal ash, which improves the oxygen release and reaction property of the coal ash itself; the samples obtained with ATP as the binder can aggregate into agglomerates, and are not easily broken. During the granulation process, when the mass fraction of ATP added is 30%, the best reaction property of Ash7-ATP3 would be obtained. The optimal reaction temperature of Ash7-ATP3 is 1 123 K, and the optimal size of reaction particles is in 0.3-<0.5 mm; the circulating oxygen release of Ash7-ATP3 is kept at about 10%. After each cycle, the mass fraction of 0.3-<0.5 mm particles is kept about 98%, indicating good wear resistance of the oxygen carrier.