Environmental Science
XU Hong-jian, WANG Shu-fang, PAN Wei-guo, GUO Rui-tang, DAI Ling-zhi, WANG Yang
2012, 32(8): 647-653.
An experimental study on defluorination process of desulphurization wastewater was carried out in a static testing apparatus based on combination of chemical coagulation and precipitation method, during which factors influencing the defluorination efficiency were analyzed by orthogonal tests. Results show that the defluorination property of calcium chloride is better than that of the calcium hydroxide, and the best n(Ca)/n(F) is 1∶1.3; adding an appropriate amount of coagulants may help to improve the defluorination property, such as some aluminum sulfate and iron chloride, and the best ratios of n(Al)/n(F) and n(Fe)/n(F) are respectively 1.5 and 0.6; the defluorination efficiency may get up to 95% under the premise of pH value in 5-6, temperature at 30 ℃, rotating speed at 500 r/min, and an addition of 0.1% PAM. Factors influencing the defluorination efficiency are found to be in following descending order: CaCl2, Al2(SO4)3, PAM, FeCl3, pH value ,temperature and rotating speed.