Material Science
YANG Zhen, LU Jintao, ZHAO Xinbao, YUAN Yong, YAN Jingbo,YIN Hongfei, DANG Yingying
2015, 35(10): 859-864.
The oxidation behavior of austenitic stainless steel HR3C was studied respectively in static air and pure steam for 500 h at 750 ℃ using scanning electron microscopy and X-ray diffraction, so as to investigate the oxidation mechanism of HR3C in above 2 atmospheres, based on detail characterization on the microstructure of relevant oxide scales. Results show that a continuous layer of (Cr, Mn)2O3 scale forms on the surface of HR3C in both the atmospheres; the oxidization kinetics of HRC presents a two-stage parabolic law in static air; the existance of water vapor promotes the cracking of (Cr, Mn)2O3 scale, and accelarates the oxidation of the alloy, resulting in deviated parabolic law of the HR3C growth kinetics in pure steam; the cracking of (Cr, Mn)2O3 layer is induced by the interaction of scale/alloy interfacial voids and the growth stress in the scale, which makes bare alloy directly exposed to the high-temperature air or pure steam, thus forming Fe3O4 nodules.