Abstract:
To improve the gasification effect of sewage sludge, experiments on chemical looping gasification (CLG) of sewage sludge were conducted in a fluidized bed using hematite as the oxygen carrier, so as to analyze the effects of O/C ratio, gasification temperature, steam content on the sludge gasification characteristics, and to study the physical and chemical properties of hematite in the process of continuous cycling. Results indicate that hematite can markedly enhance the gasification degree and carbon conversion rate of sewage sludge with increasing O/C ratio, the concentrations of CO and CH
4 in the syngas decrease, whereas that of H
2 firstly decreases and then increases. With the rise of gasification temperature, there is a gradual increase of CO and H
2 volumetric fraction, but a gradual decrease of CO
2 and CH
4 volumetric fraction, with a constant improvement of carbon conversion rate. The increase of steam content would lead to the decrease of CO and CH
4 volumetric fraction and to the increase of CO
2 and H
2 volumetric fraction in the syngas, as well as to the increase of carbon conversion rate. The hematite shows good reactivities in long-term operation periods.