高级检索

    一种恒温下煤粉与生物质混燃活化能求解新方法

    A New Solution for Activation Energy of Coal/Biomass Co-combustion at Constant Temperatures

    • 摘要: 通过恒温热重实验台对煤粉与生物质的混燃特性进行了研究.利用传统的lnln法和所提出的级数拟合法对实验数据进行了拟合,并比较了2种方法的拟合度和相关动力学参数.结果表明:在450~500 ℃内,针对无烟煤与玉米芯掺混比分别为9∶1、8∶2和7∶3的试样,利用lnln法求得的表观活化能为78.81 kJ/mol、75.53 kJ/mol和80.88 kJ/mol,不能反映燃料燃烧的真实情况,而利用级数拟合法求得的表观活化能为38.13 kJ/mol、24.82 kJ/mol和20.82 kJ/mol,呈现出随生物质掺混比增大,表观活化能逐渐减小的规律,与实验结果相吻合.级数拟合法比lnln法的适用范围更广,利用级数拟合法求得的不同生物质掺混比试样的表观活化能可以更好地反映恒温下煤粉与生物质混燃的难易程度.

       

      Abstract: The co-combustion characteristics of coal and biomass blends were studied on a tube furnace constant-temperature thermo-gravimetric experimental setup, during which the experiemntal results were analyzed using both conventional lnln analytics and the proposed series fitting method, and subsequently the fitting degree and relevant kinetic parameters respectively obtained by above two methods were compared as well. Results show that within the temperature range of 450-500 ℃, for sample blends with an anthracite/corncob blending ratio of 9:1, 8:2, and 7:3, the reaction activation energy calculated by lnln method is respectively 78.81 kJ/mol, 75.53 kJ/mol and 80.88 kJ/mol, which cannot reflect the actual combustion condition of the blends, while the reaction activation energy calculated by series fitting method is 38.13 kJ/mol, 24.82 kJ/mol and 20.82 kJ/mol, presenting a rule that the reaction activation energy decreases gradually with the rise of blending ratio of biomass, which fits with the experimental results. The series fitting method has a broader application scope than the lnln method, and the apparent activation energy calculated by the series fitting method at different blending ratios of biomass can better reflect the difficulty level of the co-combustion of coal/biomass blends at constant temperatures.

       

    /

    返回文章
    返回