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    347不锈钢表面堆焊690镍基合金电化学腐蚀性能研究

    Electrochemical Corrosion Property of Stainless Steel 347 with Ni-based Alloy 690 Surface Cladding

    • 摘要: 利用钨极氩弧焊(TIG)堆焊工艺在347不锈钢钢板表面堆焊690镍基合金,采用电化学测量技术,在室温、质量分数为3.5%的氯化钠溶液中,对347不锈钢基体、690镍基合金堆焊层以及2种合金堆焊接头的电化学腐蚀性能进行了研究. 借助扫描电镜(SEM)及其附带的能谱仪(EDS)对堆焊接头的微观组织和成分进行了分析,并通过光学显微镜来观察腐蚀后的表面形貌,研究堆焊接头的腐蚀机理. 结果表明:690镍基合金堆焊层的耐蚀性优于347不锈钢基体,347不锈钢基体的腐蚀速率约为堆焊层的8.4倍;堆焊接头的耐蚀性最差,其腐蚀速率约为堆焊层的11.8倍;堆焊层在熔合区附近对基体中Cr含量的稀释是导致堆焊后基体腐蚀加剧的主要原因.

       

      Abstract: Ni-based alloy 690 was deposited on the surface of stainless steel 347 by using TIG surfacing procedure, while electrochemical corrosion properties of the substrate stainless steel 347, surfacing layer alloy 690 and the welded joint were analyzed by electrochemical measurement technology in a 3.5% NaCl solution at room temperature. To study the corrosion mechanism of the welded joint, the microstructure and composition were analyzed by SEM and EDS, and the surface morphology after corrosion was characterized by optical microscope. Results show that the corrosion rate of the base metal and the welded joint is respectively 8.4 times and 11.8 times of the surfacing layer, indicating that the surfacing layer Ni-based alloy 690 has the strongest corrosion resistance, followed by the base metal stainless steel 347, and the welded joint has the poorest corrosion resistance. The dilution of Cr by surfacing layer in the base metal near fusion zone of welded joint is the main reason leading to the aggravated corrosion of the substrate stainless steel 347.

       

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