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    填料塔内喷淋氨水同时脱碳脱硫实验研究

    Experimental Research on Simultaneous Decarbonization and Desulfurization by Ammonia Solution in a Packed Column

    • 摘要: 通过在填料塔内喷淋较低质量分数的氨水,同时脱除模拟烟气中的CO2和SO2.对氨水质量分数、液气比、CO2体积分数、pH值、反应温度和SO2体积分数等影响因素进行研究,选出最佳工况进行连续循环运行,并探讨了实验参数对气溶胶排放的影响,提出控制气溶胶携带的措施.结果表明:氨水质量分数增大、液气比增大和初始CO2体积分数降低均会提高脱碳效率;pH值减小不利于CO2的脱除,但在9.6~10.2出现波动;在15~60 ℃内,35 ℃时脱碳效率最高;SO2体积分数的增大会降低脱碳效率;上述影响因素对脱硫效率影响不大,脱硫效率维持在99%以上;260 min连续循环运行的实验中,脱碳效率在5 min内达到95%以上且能维持30 min,脱硫效率在3 min内可达到近100%,且保持在92%以上.

       

      Abstract: Factors influencing the simultaneous removal of CO2 and SO2 from simulated flue gas by spraying low concentration ammonia solution into a packed column were studied, such as the ammonia concentration, liquid-gas ratio, CO2 concentration, pH value, reaction temperature and SO2 concentration, etc., after which optimum working conditions were determined for the continuous cyclic operation, while the effect of experimental parameters on the aerosol emission was analyzed, with control measures proposed for the aerosol entrainment. Results show that the CO2 removal efficiency increases with rising ammonia concentration, rising liquid-gas ratio, reducing CO2 concentration and reducing SO2 concentration; with the reduction of pH value, the CO2 removal efficiency generally reduces besides the pH value of 9.6-10.2, it keeps basically unchanged; in the temperature range of 15-60 ℃, the highest CO2 removal efficiency appears at 35 ℃. Above factors slightly affect the SO2 removal efficiency, which can be kept above 99%. In the continuous cycle operation test for 260 minutes, the CO2 removal efficiency could reach more than 95% within 5 minutes, maintaining for 30 minutes; the SO2 removal efficiency could reach almost 100% within 3 minutes, always being kept more than 92%.

       

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