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    运行参数对丙烷重整制氢的影响

    Effects of Operating Parameter on Hydrogen Production via Propane Reforming

    • 摘要: 针对简化丙烷蒸汽重整制氢方法及降低制氢成本的需求,利用COMSOL构建管壳换热器重整制氢模型,以反应器入口处热空气的温度与流速作为运行参数展开模拟,分析对丙烷蒸汽重整制氢的影响规律,获取最佳模拟工况条件。结果表明:额定工况条件下,热空气入口温度越高,反应器丙烷蒸汽重整制氢反应越充分,热空气入口温度达到900 K时,丙烷完全消耗;热空气入口速度的提升有利于丙烷蒸汽重整反应的正向进行,入口速度达到1.25 和1.5 m/s 时,丙烷完全消耗,产物氢气的质量分数均达0.099;综合考虑能耗和反应效率,系统的最佳工况为热空气入口温度900 K、入口速度1.25 m/s。

       

      Abstract: To simplify propane steam reforming process and reduce hydrogen production cost, a shell-and-tube heat exchanger reforming reactor model was constructed using COMSOL. The temperature and velocity of hot air at the reactor inlet were selected as operating parameters. Simulations were conducted to analyze their effects on propane steam reforming and to determine the optimal operating conditions. Results show that under rated conditions, a higher hot-air inlet temperature promotes more complete propane reforming. Propane is fully consumed when the inlet temperature reached 900 K. Increasing the hot-air inlet velocity also favors the forward steam reforming reaction. At inlet velocities of 1.25 m/s and 1.5 m/s, propane is completely converted, with hydrogen mass fractions reaching 0.099 in both cases. Considering both energy consumption and reaction efficiency, the optimal operating condition is 900 K and 1.25 m/s.

       

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