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    TP347H FG耐热钢超超临界机组服役50 000 h后组织与力学性能研究

    Study on Microstructure and Mechanical Properties of Heat Resistant Steel TP347H FG in Ultra-supercritical Unit After 50 000 Hours of Service

    • 摘要: 为研究TP347H FG管材高温服役安全性,对某600 ℃超超临界火电机组工况环境热暴露50 000 h的TP347H FG管材微观组织、腐蚀产物及力学性能进行了研究。采用金相显微镜、X射线衍射、扫描电子显微镜及能谱分析等测试手段,对服役后工件的管壁内外侧晶粒度、腐蚀机制、拉伸性能进行了综合分析。结果表明:相较于未服役工件,服役后工件表层出现晶粒细化层厚度降低现象;向火侧与背火侧氧化层均呈现双层结构,在高温烟气环境下有效增强了材料耐蚀性能;向火侧与背火侧由于晶内细小析出相的析出,其屈服极限相较于未服役管材有所提高,但析出相弱化了晶界的作用,致使工件延伸率大幅降低,并出现局部脆性断裂的特征。

       

      Abstract: To investigate the high-temperature service safety of TP347H FG pipe material, a study was conducted on the microstructure, corrosion products, and mechanical properties of TP347H FG pipe material exposed to a thermal environment of a 600 ℃ ultra-supercritical thermal power unit for 50 000 hours. A comprehensive analysis was conducted on the grain size of the inner and outer walls of the workpiece, the corrosion mechanism, and the tensile properties after service, using metallographic microscopy, X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy analysis. Results show that the surface of the service-exposed workpiece shows a reduction in the thickness of the grain refinement layer, compared to the as-received workpiece. Both the fire-facing side and the non-fire-facing side oxidation layers exhibit a double-layer structure, which effectively enhances the corrosion resistance of the material in high-temperature flue gas environment. Due to the precipitation of fine intragranular phases of both the fire-facing side and the non-fire-facing side, the yield limit is improved compared to the as-received pipe material. However, the precipitation phases weaken the role of the grain boundaries, resulting in a significant reduction in the elongation of the workpiece and the emergence of local brittle fracture.

       

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